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V-70, Azo Initiator

Wako 1st Grade
Specification Assay :
95.0+% (After Drying)
Manufacturer :
FUJIFILM Wako Chemicals U.S.A. Corporation
Storage Condition :
FREEZE -20 C
CAS RN® :
15545-97-8
Molecular Formula :
C16H28N4O2
Molecular Weight :
308.43
GHS :
  • Structural Formula
  • Label
  • Packing
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Certificate of Analysis
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LB-V70-5GS
5 G
List Price
80.00 USD

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Spectral Data
Certificate of Analysis
Calibration Certificate

Applications

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Plastics manufacturing
Photocurable


V-70 is an oil-soluble azo polymerization initiator of which a 10-hour half-life temperature is 30 ℃.
V-70 can be used as a polymerization initiator for different types of vinyl monomers and a catalyst for organic radical reactions at a low temperature.

  • Oil-soluble azo initiator having low decomposition temperature. An alternative to photoreaction as a radical generator.
  • Soluble in various organic solvents
  • With highest polymerization activity among azo initiators available in Wako
  • 10 Hour half-life decomposition temperature; 30℃

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References

  1. Tsuji, S., Aoki, T., Ushio, S., and Tanaka, T.: Synthesis and Aggregation Behavior of Temperature- and pH-Responsive Glycopolymers as Sugar-Displaying Conjugates. Polymers (Basel), 12(4), 956 (2020). PMID: 32326017
  2. Böhmová, E., Pola, R., Pechar, M., Parnica, J., Machová, D., Janoušková, O., and Etrych, T.: Polymer Cancerostatics Containing Cell-Penetrating Peptides: Internalization Efficacy Depends on Peptide Type and Spacer Length. Pharmaceutics., 12(1), 59 (2020). PMID: 31936737
  3. Kramer, S., Svatunek, D., Alberg, I., Gräfen, B., Schmitt, S., Braun, L., van Onzen, A. H. A. M., Rossin, R., Koynov, K., Mikula, H., and Zentel, R.: HPMA-Based Nanoparticles for Fast, Bioorthogonal iEDDA Ligation. Biomacromolecules, 20(10), 3786-3797 (2019). PMID: 31535846
  4. Shae, D., Becker, K. W., Christov, P., Yun, D. S., Lytton-Jean, A. K. R., Sevimli, S., Ascano, M., Kelley, M., Johnson, D. B., Balko, J. M., and Wilson, J. T.: Endosomolytic polymersomes increase the activity of cyclic dinucleotide STING agonists to enhance cancer immunotherapy. Nat Nanotechnol., 14(3), 269-278 (2019). PMID: 30664751
  5. Hinman, A., Holst, C. R., Latham, J. C., Bruegger, J. J., Ulas, G., McCusker, K. P., Amagata, A., Davis, D., Hoff, K. G., Kahn-Kirby, A. H., Kim, V., Kosaka, Y., Lee, E., Malone, S. A., Mei, J. J., Richards, S. J., Rivera, V., Miller, G., Trimmer, J. K., and Shrader, W. D.: Vitamin E hydroquinone is an endogenous regulator of ferroptosis via redox control of 15-lipoxygenase. PLoS One, 13(8):e0201369 (2018). PMID: 30110365
  6. Banerjee, S., Bellan, E. V., Gayet, F., Debuigne, A., Detrembleur, C., Poli, R., Améduri, B., and Ladmiral, V.: Bis(formylphenolato)cobalt(II)-Mediated Alternating Radical Copolymerization of tert-Butyl 2-Trifluoromethylacrylate with Vinyl Acetate. Polymers (Basel), 9(12), 702 (2017). PMID: 30966002
  7. Beziau, A., De, Menezes, R. N. L., Biswas, S., Singh, A., Cuthbert, J., Balazs, A. C., Kowalewski, T., and Matyjaszewski, K.: Combining ATRP and FRP Gels: Soft Gluing of Polymeric Materials for the Fabrication of Stackable Gels. Polymers (Basel), 9(6), 186 (2017). PMID: 30970867
  8. Lokhmatikov, A. V., Voskoboynikova, N., Cherepanov, D. A., Skulachev, M. V., Steinhoff, H. J., Skulachev, V. P., and Mulkidjanian, A. Y.: Impact of Antioxidants on Cardiolipin Oxidation in Liposomes: Why Mitochondrial Cardiolipin Serves as an Apoptotic Signal? Oxid Med Cell Longev., 2016:8679469 (2016). PMID: 27313834
  9. Correa, C. R., Chen, C. Y., Aldini, G., Rasmussen, H., Ronchi, C. F., Berchieri-Ronchi, C., Cho, S. M., Blumberg, J. B., and Yeum, K. J.: Bioavailability of plant pigment phytochemicals in Angelica keiskei in older adults: A pilot absorption kinetic study. Nutr Res Pract., 8(5):550-7 (2014). PMID: 25324936
  10. Nagai, M., Tani, M., Kishimoto, Y., Iizuka, M., Saita, E., Toyozaki, M., Kamiya, T., Ikeguchi, M., and Kondo, K.: Sweet potato (Ipomoea batatas L.) leaves suppressed oxidation of low density lipoprotein (LDL) in vitro and in human subjects. J Clin Biochem Nutr., 48(3), 203-8 (2011). PMID: 21562639

Overview / Applications

Outline V-70 is an oil-soluble azo polymerization initiator of which 10-hour half-life temperature is 30 ºC.
V-70 can be used as a polymerization initiator for different types of vinyl monomers and a catalyst for organic radical reactions at a low temperature.

Property

Appearance nearly white, crystalline powder
*Contains water.
Specificity 10-hour half life temperature: 30 ºC (Toluene)
Solubility dichloromethane: freely soluble.
acetonitrile, N,N-Dimethylformamide: soluble.
methanol, acetone, toluene: slightly soluble.
Melting Point 50-96 °C

Manufacturer Information

Alias

  • 2,2'-Azobis(4-methoxy-2,4-dimethylvaleronitrile)

Author : [WKUS] Naomi Tsurutani

For research use or further manufacturing use only. Not for use in diagnostic procedures.

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