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(R)-BINAP-TMPTA Polymer

for Organic Synthesis
Manufacturer :
FUJIFILM Wako Pure Chemical Corporation
Storage Condition :
Keep at RT.
CAS RN® :
1159341-66-8
  • Structural Formula
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SDS
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Distributor
027-16661
Barcode No
4987481499973
100mg
List Price
127.00 USD

Out of Stock

Distributor
023-16663
Barcode No
4987481499980
500mg
List Price
473.00 USD

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Document

SDS
Product Specification Sheet
Spectral Data
Certificate of Analysis
Calibration Certificate

Overview

BINAP is one of popular ligand in asymmetric synthesis. In decade, recovery and recycling of catalysts and ligands have been studied from an environmental point of view. There are various types of immobilized catalyst and ligands, but many complicated purification/work-up were often necessary.
BINAP-TMPTA can be easily synthesized and can be used in organic synthesis reaction. In addition, the Pd catalyzed reaction using BINAP-TMPTA gives results which show similar results as conventional non-polymerized BINAP/Pd catalyst.

Features

  • Has potent asymmetric induction ability.
  • Has high solvent resistance and can be used with most solvents.
  • After reaction, it can be recovered and reusable without leaching.
  • (Store under an inert gas atmosphere when kept without leaching.)

Applications

Preparation of Polymer BINAP-Ru-Activated Catalyst 1)

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Asymmetric Hydrogenation of Methyl Acetoacetate

In the above reaction, the isolated yield and optical purity both remain 95% or higher after up to 7 reactions.

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Asymmetric Hydrogenation of Itaconic Acid 1)

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References
  1. Y. Takamatsu, G. Goshima, N. Takenaka, K. Toribatake, H. Shibaguchi,T. Nagano, T. Shimada: The First Inetrnational Symposium on Process Chemistry, 1P-47, June 28-30 (2008).

Overview / Applications

Property

Manufacturer Information

Alias

  • (R)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl-(1,1,1-Trimethylolpropane Triacrylate) Polymer

Author : Y. Takeshima

For research use or further manufacturing use only. Not for use in diagnostic procedures.

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