Ethyl O-Benzenesulfonylacetohydroxamate
- for Organic Synthesis
- Specification Assay :
- 97.0+% (HPLC)
- Manufacturer :
- FUJIFILM Wako Pure Chemical Corporation
- Storage Condition :
- Keep at -20 degrees C.
- CAS RN® :
- 2097677-32-0
- Molecular Formula :
- C10H13NO4S
- Molecular Weight :
- 243.28
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- Structural Formula
- Label
- Packing
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5G
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In stock in Japan |
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25G
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In stock in Japan |
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Document
Features
- Relatively stable and storable*
- Various functional group conversions are possible
- Reacts under mild conditions in the presence of acid catalyst
*freeze storage
Applications
Nitrile Synthesis from Aldehydes
Intermediate synthesis of anticancer drug Tarceva
Amide Synthesis from Ketones
Synthesis of candidate drugs for breast cancer
Deacetylative Amination of Acetyl Arenes and Alkanes
Scope of Acetyl Arenes Used
Scope of the Aliphatic Methyl Ketones Used
Synthesis of Baclofen and Rolipram
References
- "Brønsted Acid Catalyzed Nitrile Synthesis from Aldehydes Using Oximes via Transoximation at Ambient Temperature"
Hyodo, K., Togashi, K., Oishi, N., Hasegawa, G. and Uchida, K. : Org. Lett., 19, 3005 (2017).
https://doi.org/10.1021/acs.orglett.7b01263 - "Direct and Catalytic Amide Synthesis from Ketones via Transoximation and Beckmann Rearrangement under Mild Conditions"
Hyodo, K., Hasegawa, G., Oishi, N., Kuroda, K. and Uchida, K. : J. Org. Chem., 83, 13080 (2018).
https://doi.org/10.1021/acs.joc.8b01810 - "Deacetylative Amination of Acetyl Arenes and Alkanes with C−C Bond Cleavage"
Hyodo, K., Hasegawa, G., Maki, H. and Uchida, K. : Org. Lett., 21, 2818 (2019).
https://doi.org/10.1021/acs.orglett.9b00807
Overview / Applications
Property
Manufacturer Information
Alias
For research use or further manufacturing use only. Not for use in diagnostic procedures.
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