4-(4,6-Dimethoxy-1,3,5-triazin-2-yl)-4-methylmorpholinium Chloride n-Hydrate
- for Organic Synthesis
- Specification Assay :
- 98.0 - 102.0% (calculated on the anhydrous basis)
- Manufacturer :
- FUJIFILM Wako Pure Chemical Corporation
- Storage Condition :
- Keep at 2-10 degrees C.
- CAS RN® :
- 3945-69-5(Anhy)
- Molecular Formula :
- C10H17ClN4O3・nH2O
- Molecular Weight :
- (C10H17ClN4O3=276.72)
- GHS :
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- Structural Formula
- Label
- Packing
- SDS
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Comparison
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5G
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In stock in Japan |
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25G
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In stock in Japan |
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100G
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In stock in Japan |
※Check availability in the US with the distributor.
Document
Overview
The most general method to obtain amide or ester compounds is dehydration condensation reaction with activation of carboxylic acid. In general, carbodiimides (WSC, DCC) are widely used as a condensing agent from the viewpoint of reactivity and economic efficiency. However they have drawbacks such as skin sensitization and removal of by-products from reaction mixture.
The novel triazine condensing agent (DMT-MM) shown in here can be used under similar reaction conditions as WSC and DCC. And also, DMT-MM can be used in water or aprotic solvent. The condensation reaction proceeds in hydrous organic solvents and there is no need to dehydrate solvents.
Features
- Useful for esterification, amidation and peptide synthesis
- In amidation, water and lower alcohols such as methanol can be used as a reaction solvent.
- Possible to do base-free reaction using DMT-MM
- By-products are water-soluble and can be easily removed by washing with water at extraction/separation.
Applications
Amide synthesis in alcohol
References
- Kunishima, M., Kawachi, C., Morita, J., Terao, K., Iwasaki, F. and Tani, S.: Tetrahedron, 55, 13159 (1999).
- M. Kunishima, C. Kawachi, K. Hioki, K. Terao, S. Tani: Tetrahedron, 57, 1551（2001）.
Overview / Applications
| Outline | This product is for research use only. Do not administer it to human.
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| Precautions for Use | Packed on argon gasb |
Property
| Appearance | White - slightly brown, powder or mass |
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Manufacturer Information
Alias
- DMT-MM
For research use or further manufacturing use only. Not for use in diagnostic procedures.
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