p-(Trimethylsilyl)phenylmethanethiol

for Organic Synthesis

Specification Assay :: 90.0+% (HPLC)

Manufacturer :: FUJIFILM Wako Pure Chemical Corporation

Storage Condition :: Keep at 2-10 degrees C.

CAS RN^® :: 57337-85-6
Molecular Formula :: (CH3)3SiC6H4CH2SH
Molecular Weight :: 196.38

GHS :

Structural Formula
Label
Packing

SDS

Comparison	Product Number	Package Size	Price	Availability	Certificate of Analysis	Purchase
	Distributor 206-15971 Barcode No 4987481429482	10mL	List Price 617.00 USD	Out of Stock Inquire		Distributor

※Check availability in the US with the distributor.

Document
Overview / Applications
Property
Same CAS list

Document

SDS

Product Specification Sheet

Overview / Applications

Outline	This product is for research use only. Do not administer it to human. [Green Chemistry]Sulfur Compounds with Less Odor These sulfur compounds with less odor are made by replacing one of alkyl chains bound to a sulfur atom by a dodecyl radical. Each has less volatility and smells less disagreeable.Recently, sulfur compounds with less odor have been investigated1^{) 2)}, and Sulfide and Sulfoxide are each applicable to alcohol oxidation reaction, typified by Corey-Kim oxidation and Swern oxidation. Especially in Corey-Kim oxidation, the reaction progresses even in solvents that are easy to treat. Moreover, Sulfide can be applied to dealkylation of ethers and esters. Sulfonium salt can also be used as a methylation agent for micell formation^{4) 5)}in addition to synthesis of oxirane3⁾.Thiol introduced the trimethylsilyl (TMS) group, which readily induces functional group conversion, to the benzene ring will be released soon⁶⁾. [References] K. Nishide, S. Ohsugi, H. Shiraki, H. Tamakita, M. Node : Org. Lett., 3, 3121 (2001). M. Node, K. Kumar, K. Nishide, S. Ohsugi, T. Miyamoto : Tetrahedron Lett., 42, 9207 (2001). Y. Yano, T. Okonogi, M. Sunaga, W. Tagaki : J. Chem. Soc., Chem. Commun., 527 (1973). K. Yamauchi, Y. Hisanaga, M. Kinoshita : J. Am. Chem. Soc., 105, 538 (1983), K. Yamauchi, Y. Hisanaga, M. Kinoshita :J. Chem. Soc. Perkin Trans. 1, 1941 (1983). K. Nishide, T. Miyamoto, K. Kumar, S. Ohsugi, M. Node : Tetrahedron Lett., 43, 8569 (2002).
Precautions for Use	Packed on argon gas

Outline

This product is for research use only. Do not administer it to human.

[Green Chemistry]Sulfur Compounds with Less Odor

These sulfur compounds with less odor are made by replacing one of alkyl chains bound to a sulfur atom by a dodecyl radical. Each has less volatility and smells less disagreeable.Recently, sulfur compounds with less odor have been investigated1^{) 2)}, and Sulfide and Sulfoxide are each applicable to alcohol oxidation reaction, typified by Corey-Kim oxidation and Swern oxidation. Especially in Corey-Kim oxidation, the reaction progresses even in solvents that are easy to treat. Moreover, Sulfide can be applied to dealkylation of ethers and esters. Sulfonium salt can also be used as a methylation agent for micell formation^{4) 5)}in addition to synthesis of oxirane3⁾.Thiol introduced the trimethylsilyl (TMS) group, which readily induces functional group conversion, to the benzene ring will be released soon⁶⁾.

[References]

K. Nishide, S. Ohsugi, H. Shiraki, H. Tamakita, M. Node : Org. Lett., 3, 3121 (2001).
M. Node, K. Kumar, K. Nishide, S. Ohsugi, T. Miyamoto : Tetrahedron Lett., 42, 9207 (2001).
Y. Yano, T. Okonogi, M. Sunaga, W. Tagaki : J. Chem. Soc., Chem. Commun., 527 (1973).
K. Yamauchi, Y. Hisanaga, M. Kinoshita : J. Am. Chem. Soc., 105, 538 (1983),
K. Yamauchi, Y. Hisanaga, M. Kinoshita :J. Chem. Soc. Perkin Trans. 1, 1941 (1983).
K. Nishide, T. Miyamoto, K. Kumar, S. Ohsugi, M. Node : Tetrahedron Lett., 43, 8569 (2002).

Precautions for Use

Packed on argon gas

Property

Appearance	Colorless - nearly colorless, clear liquid

Same CAS list

For research use or further manufacturing use only. Not for use in diagnostic procedures.

Product content may differ from the actual image due to minor specification changes etc.

If the revision of product standards and packaging standards has been made, there is a case where the actual product specifications and images are different.