(Dimethylphenylsilyl)boronic Acid Pinacol Ester
- for Organic Synthesis
- Specification Assay :
- 90.0+% (capillary GC)
- Manufacturer :
- FUJIFILM Wako Pure Chemical Corporation
- Storage Condition :
- Keep at RT.
- CAS RN® :
- 185990-03-8
- Molecular Formula :
- C14H23BO2Si
- Molecular Weight :
- 262.23
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- Structural Formula
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1G
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In stock in Japan |
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5G
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In stock in Japan |
※Check availability in the US with the distributor.
Document
Sila-Borylation
Because of the usefulness of Suzuki-Miyaura reaction, the carbon-boron bond formation is one of the key reactions in the synthesis for pharmaceuticals and functional materials. However, in order to synthesize pinacolatoborane, B(pin), by the usual borylation reaction, improvement is required because expensive noble metal catalyst is often used. This product gives pinacolatoborane without using transition metal catalyst.
Features
- B(pin) can be synthesized under basic condition without transition metal catalyst.
- Formation of B(pin) can also be carried out with a sterically bulky substrate.
- Applicable to asymmetric synthesis by silyl borylation for alkyne.
Applications
Borylation of arylharide
References
- Amamoto, E., Izumi, K., Horita, Y. and Ito, H.: J. Am. Chem. Soc., 134, 19997 (2012).
- Ito, H., Horita, Y. and Yamamoto, E.: Chem. Commun., 48, 8006 (2012).
- Gryparis, C. and Stratakis, M.: Org. Lett., 16, 1430 (2014).
- Miura, T., Nishida, Y. and Murakami, M.: J. Am. Chem. Soc., 136, 6223 (2014).
Overview / Applications
| Outline | This product is for research use only. Do not administer it to human.
[Yamamoto, E., Izumi, K., Horita, Y. and Ito, H.: J. Am. Chem. Soc., 134, 19997 (2012).] |
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| Precautions for Use | Packed on argon gas |
Property
| Appearance | Colorless - pale yellowish brown, clear - slightly muddy liquid |
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Manufacturer Information
Alias
For research use or further manufacturing use only. Not for use in diagnostic procedures.
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