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TriBOT [2,4,6-tris(benzyloxy)-1,3,5-triazine]

Manufacturer :
NARD Chemicals
Storage Condition :
Keep at RT.
CAS RN® :
7285-83-8
Molecular Formula :
C24H21N3O3
  • Structural Formula
Comparison
Product Number
Package Size
Price
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Distributor
387-02181
Manufacturer
387-02181
100G
List Price
404.00 USD

Out of Stock

Overview

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This product is used for p-methoxybenzylation of hydroxy group under acidic conditions such as trifluoromethanesulfonic acid. It is stable against humidity or air and can be stored at room temperature for long-term. One molecule has 3 benzyl groups, so 1 equivalent of TriBOT-PM react 3 equivalent of OH group.

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Features

  • Air-Stable Solid
  • Easy handling, just mixing at room temperature
  • Having long shelf life at room temperature
  • One molecule has 3 reactive sites
  • High atom economy

Applications

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Overview / Applications

Outline This product is for research use only. Do not administer it to human.


A novel acid-catalyzed O-benzylating reagent with the smallest unit of imidate structure.
The reaction of various functionalized alcohols with 0.4 equiv. of TriBOT in the presence of trifluoromethanesulfonic acid afforded the benzyl ethers in good yields. TriBOT is an inexpensive stable crystalline solid with high atom economy.


Reference: Yamada, K., Fujita, H. and Kunishima, M., Org. Lett., 14 (19), 5026-9 (2012)

For research use or further manufacturing use only. Not for use in diagnostic procedures.

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