(1,5-Cyclooctadiene)(pyridine)(tricyclohexylphosphine)iridium(I) Hexafluorophosphate

for Organic Synthesis

Manufacturer :: FUJIFILM Wako Pure Chemical Corporation

Storage Condition :: Keep at RT.

CAS RN^® :: 64536-78-3
Molecular Formula :: C31H50F6IrNP2
Molecular Weight :: 804.89

GHS :

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Comparison	Product Number	Package Size	Price	Inventory
	Distributor 034-23201 Barcode No 4548995022356	100mg	List Price JPY 13,300	Inquire	Certificate of Analysis
	Distributor 030-23203 Barcode No 4548995022363	500mg	List Price JPY 44,800	In stock in Japan	Certificate of Analysis

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500mg

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Overview / Applications

Outline	This product is for research use only. Do not administer it to human. It is one of homogeneous hydrogenation catalysts and is known as the Crabtree's catalyst¹⁾. As the Crabtree's catalyst is a cationic complex, it binds to coordinating functional groups such as the hydroxyl group, causing the surface-selective hydrogenation of a double bond. In addition, although it is generally difficult to reduce low-reacting tetrasubstituted olefins using the Wilkinson's catalyst, the Crabtree's catalyst allows the progression of these reactions of the tetrasubstituted olefins. Reference 1) Crabtree, R. H and Davis, M. W.: J. Org. Chem., 51, 2655(1986).
Precautions for Use	Packed on argon gas

Outline

This product is for research use only. Do not administer it to human.

It is one of homogeneous hydrogenation catalysts and is known as the Crabtree's catalyst¹⁾.
As the Crabtree's catalyst is a cationic complex, it binds to coordinating functional groups such as the hydroxyl group, causing the surface-selective hydrogenation of a double bond. In addition, although it is generally difficult to reduce low-reacting tetrasubstituted olefins using the Wilkinson's catalyst, the Crabtree's catalyst allows the progression of these reactions of the tetrasubstituted olefins.
Reference 1) Crabtree, R. H and Davis, M. W.: J. Org. Chem., 51, 2655(1986).

Precautions for Use

Packed on argon gas

Property

Appearance	Pale yellow - yellowish red, crystalline powder - powder

Manufacturer Information

Alias

Same CAS list

Related Information

Product List

Product Name
Iridium(IV) Oxide	Practical Grade
Iridium(III) Chloride
Iridium(IV) Chloride
Iridium(IV) Chloride, 99.5%
(Acetylacetonato)(1,5-cyclooctadiene)iridium(I)
Ammonium Hexachloroiridate(IV)	Wako 1st Grade
(R)-Chloro[(1,2,3,4,5-η)-1,2,3,4,5-pentamethyl-2,4-cyclopentadien-1-yl](2-pyrrolidinecarboxamido-κN1,κN2)iridium(Ⅲ)	for Organic Synthesis
(S)-Chloro[(1,2,3,4,5-η)-1,2,3,4,5-pentamethyl-2,4-cyclopentadien-1-yl](2-pyrrolidinecarboxamido-κN1,κN2)iridium(Ⅲ)	for Organic Synthesis
Potassium Hexachloroiridate(IV)	Wako 1st Grade
Di-μ-methoxobis(1,5-cyclooctadiene)diiridium(Ⅰ)	for Organic Synthesis
Di-mu-chlorobis[(eta-cycloocta-1,5-diene)iridium (I)]	Wako 1st Grade
Di-μ-chlorobis[(η-cycloocta-1,5-diene)iridium(Ⅰ)]	for Organic Synthesis
Pentamethylcyclopentadienyliridium(III) Dichloride Dimer
Chlorobis(cyclooctene)iridium(I) Dimer
Bis(1,5-cyclooctadiene)iridium(I) Tetrakis[3,5-bis(trifluoromethylphenyl)]borate Discontinued
Hydrogen Hexachloroiridate(IV) n-Hydrate	Wako 1st Grade
Potassium Hexachloroiridate(III) n-Hydrate	Wako 1st Grade
Sodium Hexachloroiridate(IV) n-Hydrate	Wako 1st Grade
Iridium Acetate	for Organic Synthesis

For research use or further manufacturing use only. Not for use in diagnostic procedures.

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