1,1'-(Azodicarbonyl)dipiperidine

for Organic Synthesis

Specification Assay :: 97.0+% (HPLC)

Manufacturer :: FUJIFILM Wako Pure Chemical Corporation

Storage Condition :: Keep at RT.

CAS RN^® :: 10465-81-3
Molecular Formula :: C12H20N4O2
Molecular Weight :: 252.31

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Product Number	Package Size	Price	Inventory
Distributor 010-25761 Barcode No 4548995034755	5G	Inquire	Inquire	Certificate of Analysis
Distributor 018-25762 Barcode No 4548995034762	25G	Inquire	Inquire	Certificate of Analysis
Distributor 016-25763 Barcode No 4548995034779	100G		Discontinued	Certificate of Analysis

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Overview / Applications

Outline	This product is a reagent used for the Mitsunobu reaction and is known as the ADDP. Even reactions for amides with 11≥pKa that are hard to proceed with the DEAD can proceed with this product.¹⁾ In addition, by using this product and azides, synthesis of amino acids having a substituent at α-position of the carboxylic acid has been reported.²⁾ Reference : 1) Tsunoda, T., Yamamiya, Y., Ito, S.: Tetrahedron Lett., 34, 1639 (1993). 2) Green, J. E., Bender, D. M., Jackson, S., O'Donnell, M. J. and McCarthy, J. R.: Org. Lett., 11, 807 (2009). This product is for research use only. Do not administer it to human.
Precautions for Use	Packed on argon gas

Outline

This product is a reagent used for the Mitsunobu reaction and is known as the ADDP.
Even reactions for amides with 11≥pKa that are hard to proceed with the DEAD can proceed with this product.¹⁾ In addition, by using this product and azides, synthesis of amino acids having a substituent at α-position of the carboxylic acid has been reported.²⁾

Reference :
1) Tsunoda, T., Yamamiya, Y., Ito, S.: Tetrahedron Lett., 34, 1639 (1993).
2) Green, J. E., Bender, D. M., Jackson, S., O'Donnell, M. J. and McCarthy, J. R.: Org. Lett., 11, 807 (2009).
This product is for research use only. Do not administer it to human.

Precautions for Use

Packed on argon gas

Property

Appearance	Yellow - yellowish red, crystals - powder

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Same CAS list

For research use or further manufacturing use only. Not for use in diagnostic procedures.

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