m-Benzenediboronic Acid Pinacol Ester, 1,8-Diaminonaphthalene, Protected

for Organic Synthesis

Specification Assay :: 95.0+% (capillary GC)

Manufacturer :: FUJIFILM Wako Pure Chemical Corporation

Storage Condition :: Keep at 2-10 degrees C.

CAS RN^® :: 950511-17-8
Molecular Formula :: C22H24B2N2O2
Molecular Weight :: 370.06

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Comparison	Product Number	Package Size	Price	Inventory
	Distributor 028-16711 Barcode No 4987481610583	1G		Discontinued	Certificate of Analysis
	Distributor 024-16713 Barcode No 4987481610590	5G	List Price JPY 71,500	Inquire	Certificate of Analysis

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Overview / Applications

Outline	This product is for research use only. Do not administer it to human. *Boronic Acid 1,8-Diaminonaphthalene (B(dan)) Protecting Reagents* Suzuki-Miyaura coupling reaction which synthesize biaryl compound from Arylboronic acid and Aryl halide by addition of catalyst to transition metal is very beneficial and one of the most commonly used reaction in late years. The products are protected by 1,8-Diaminonaphthalene from boronic acid and thus useful for synthesis of oligoarenes. Processing 1,8-Diaminonaphthalene with acidic aqueous solution facilitates deprotection. Features: Deprotection with acidic aqueous solution --- to boronic acid Useful for synthesis of oligoarenes References Noguchi H., Shioda T., Chou C.-M. and Suginome M.: Org. Lett., 10, 377 (2008). Noguchi H., Hoji K. and Suginome M.: J. Am. Chem. Soc., 129, 758 (2007)
Precautions for Use	Packed on argon gas

Outline

This product is for research use only. Do not administer it to human.

Boronic Acid 1,8-Diaminonaphthalene (B(dan)) Protecting Reagents

Suzuki-Miyaura coupling reaction which synthesize biaryl compound from Arylboronic acid and Aryl halide by addition of catalyst to transition metal is very beneficial and one of the most commonly used reaction in late years.
The products are protected by 1,8-Diaminonaphthalene from boronic acid and thus useful for synthesis of oligoarenes. Processing 1,8-Diaminonaphthalene with acidic aqueous solution facilitates deprotection.

Features:

Deprotection with acidic aqueous solution --- to boronic acid

Useful for synthesis of oligoarenes

References

Noguchi H., Shioda T., Chou C.-M. and Suginome M.: Org. Lett., 10, 377 (2008).

Noguchi H., Hoji K. and Suginome M.: J. Am. Chem. Soc., 129, 758 (2007)

Precautions for Use

Packed on argon gas

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2,3-Dihydro-1H-naphtho[1,8-de]-1,3,2-diazaborinyl-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzene
2,3-dihydro-2-[3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]-1H-Naphtho[1,8-de]-1,3,2-diazaborine

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For research use or further manufacturing use only. Not for use in diagnostic procedures.

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